public catalogue · open access · last index pass 2026-05-08 08:14:02 UTChost: cat-pub-04 · build 0.14.3-prototype · rev rA9F2
overviewcatalogueAM-2012-00833-A

AM-2012-00833-A · Pyrrhotite, anomalous magnetic responsearchived

physical & structuralrev. 4
designationPyrrhotite, anomalous magnetic response
chemical formulaFe₁₋ₓS
classificationSulfide / Pyrrhotite group
crystal systemMonoclinic
mohs hardness3.5 – 4.5
density (g/cm³)4.61
colourBronze yellow, tarnishing brown
type localitySudbury basin, Ontario, Canada
raman spectroscopy532 nm · pass A
200400600800100012001400Raman shift (cm⁻¹)intensity (arb.)218286339376
λ_excitation: 532 nm · acq. 3 × 10 s · grating 1800 g/mmfig. 1 · raman.am-2012-00833-a.svg

reported peaks (cm⁻¹): 218, 286, 339, 376

notessubmitter remarks + registry

Four-probe magnetometry indicates persistent magnetisation following thermal demagnetisation cycles to 400 K. Behaviour is inconsistent with the stoichiometric vacancy fraction reported by EDX. The demagnetisation curve is non-Arrhenius. Specimen has been re-tested at three independent facilities; results agree within experimental uncertainty. No mechanism has been advanced.