public catalogue · open access · last index pass 2026-06-30 08:14:02 UTChost: cat-pub-04 · build 0.14.3-prototype · rev rA9F2
overviewcatalogueAM-2016-00744-A

AM-2016-00744-A · Fluorite with ordered defect arrayarchived

physical & structuralrev. 3
designationFluorite with ordered defect array
chemical formulaCaF₂
classificationHalide / Fluorite group
crystal systemCubic
mohs hardness4
density (g/cm³)3.18
colourColourless to pale green
type localityBerbes, Asturias, Spain
raman spectroscopy532 nm · pass A
200400600800100012001400Raman shift (cm⁻¹)intensity (arb.)322612
λ_excitation: 532 nm · acq. 3 × 10 s · grating 1800 g/mmfig. 1 · raman.am-2016-00744-a.svg

reported peaks (cm⁻¹): 322, 612

notessubmitter remarks + registry

TEM imaging of an extracted lamella reveals a regular array of point defects with apparent long-range correlation, on a length scale of approximately 12 nm. Mechanical perturbation by uniaxial compression to 2 GPa does not disrupt the alignment. The defect lattice re-establishes within ~6 hours of perturbation as confirmed by repeat TEM. Mechanism not understood. The 612 cm⁻¹ Raman feature is the same wavenumber as the unattributed band reported in AM-2019-04471-A.

chain of custody8 events · 5 seal-breaks

Events recorded against this accession in the registry's printed custody book. Operator initials are anonymous. Storage codes follow the convention vault-shelf-drawer.

timestampstagedetailop.
2016-03-30 14:24 UTCintakeweighed, dimensioned, photographed; container sealed and labelled with the accession identifierR.E.
2016-03-31 13:48 UTCpass Avisual inspection · density (Archimedes) · mass to ±0.01 gS.W.
2016-04-08 11:40 UTCpass BRaman acquisition; 2 peaks above prominence threshold
instrument: Renishaw inVia (785 nm)
ref. checked: COD entry 149689
S.W.
2016-04-10 12:53 UTCstoragere-bagged, label re-printed; placed in vault B, shelf 11, drawer 13R.E.
2018-04-10 10:33 UTCre-inspectionseal intact · label legible · no visible degradationC.B.
2020-04-09 16:44 UTCre-inspectionseal intact · label legible · no visible degradationC.B.
2022-04-09 09:02 UTCre-inspectionseal intact · label legible · no visible degradationC.B.
2024-04-08 14:41 UTCre-inspectionseal intact · label legible · no visible degradationC.B.

physical location: vault B · shelf 11 · drawer 13 · last documented inspection: 2024-04-08 14:41 UTC